2D 7Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings.

نویسندگان

  • G Hamdoun
  • B Gouilleux
  • M Sebban
  • G Barozzino-Consiglio
  • A Harrison-Marchand
  • P Giraudeau
  • J Maddaluno
  • H Oulyadi
چکیده

The measurement of small homonuclear 2J7Li-7Li scalar couplings relying on constant time (CT) COSY NMR suffers from strong time limitations. We describe the first Ultrafast CT COSY experiment on lithium 7, which provides a considerable acceleration in the study of the aggregation state and dynamics of n-BuLi/MeLi complexes.

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عنوان ژورنال:
  • Chemical communications

دوره 53 1  شماره 

صفحات  -

تاریخ انتشار 2016